| Unlock This | How to Unlock |
| Pang De |
complete Ma Chao musou mode |
| Cao Ren |
complete Cao Pi musou mode |
| Sima Yi |
complete any 1 Wei musou mode |
| Xiahou Yaun |
complete Xiahou Dun's musou mode |
| Zhang He |
complete any 2 Wei musou modes |
| Xu Huang |
complete any 3 Wei musou modes |
| Cao Cao |
complete any 4 Wei musou modes |
| Guan Ping |
complete Guan Yu musou mode |
| Wei Yan |
complete Huang Zhong musou mode |
| Yue Ying |
complete Zhuge Liang musou mode |
| Zhuge Liang |
complete any 1 Shu musou mode |
| Jiang Wei |
complete any 2 Shu musou modes |
| Pang Tong |
complete any 3 Shu musou modes |
| Liu Bei |
complete any 4 Shu musou modes |
| Gan Ning |
complete Ling Tong musou mode |
| Sun Ce |
complete Sun Quan musou mode |
| Da Qiao |
complete Sun Ce musou mode |
| Xiao Qiao |
complete Zhuo Yu musou mode |
| Zhuo Tai |
complete any 1 Wu musou mode |
| Lu Meng |
complete any 2 Wu musou modes |
| Huang Gai |
complete any 3 Wu musou modes |
| Sun Jian |
complete any 4 Wu musou modes |
| Lu Bu |
Complete 1 Wei, 1 Shu, and 1 Wu musou modes |
| Diao Chan |
Complete Lu Bu musou mode |
| Yuan Shao |
Complete Cao Cao musou mode |
| Dong Zhuo |
complete Diao Chan musou mode |
| Zuo Ci |
Unlock every other character |
| Zhang Jiao |
Complete Liu Bei, Cao Cao, and Sun Jian's musous |
| Meng Huo |
Complete Zhuge Liang and Lu Xun's musous |
| Zhu Rong |
Complete Meng Huo's musou |
