| Unlock This | How to Unlock |
| Shu: Zhuge Liang - Lui Bei - Pang Tong | Complete Musou mode with any default Shu character. |
| Wu: Sun Jian - Sun Ce - Sun Quan | Complete Musou mode with any default Wu character. |
| Wei: Cao Cao - Cao Ren - Sima Yi | Complete Musou mode with any default Wei character. |
| Other: Yuan Shao - Dong Zhuo | Complete Musou mode once with one character from each kingdom |
| Other: Lu Bu - Diao Chan - Zhang Jiao - Meng Huo - Zhu Rong | Complete Musou mode with any default Other character. |
| Wu: Da Qiao - Xiao Qiao | Complete Musou mode with Sun Ce. |
| Wu: Zhou Tai - Huang Gai - Lu Meng | Complete Musou mode with Sun Jian |
| Shu: Jiang Wei - Huang Zhong - Wei Yan | Complete Musou mode with Liu Bei |
| Wei: Zhang He - Zhang Liao - Xu Huang | Complete Musou mode with Cao Cao |
